References

1. S.F. de Aquino, E.M.F. Brandt, C.A. de L. Chernicharo, Remoção de fármacos e desreguladores endócrinos em estações de tratamento de esgoto: Revisão da literatura, Eng. Sanit. e Ambient., 18 (2013) 187–204.
2. G.P. Pessoa, N.C. de Souza, C.B. Vidal, J.A.C. Alves, P.I.M. Firmino, R.F. Nascimento, A.B. dos Santos, Occurrence and removal of estrogens in Brazilian wastewater treatment plants, Sci. Total Environ., 490 (2014) 288–295.
3. W.A. Evans, P.J. Davies, C. McRae, The occurrence of methyl, ethyl, propyl, and butyl parabens in the urban rivers and stormwaters of Sydney, Australia, Environ. Sci. Water Res. Technol., 2 (2016) 733–742.
4. S.D. Richardson, T.A. Ternes, Water analysis: emerging contaminants and current issues, Anal. Chem., 90 (2018) 398–428.
5. C.B. Vidal, M. Seredych, E. Rodríguez-Castellón, R.F. Nascimento, T.J. Bandosz, Effect of nanoporous carbon surface chemistry on the removal of endocrine disruptors from water phase, J. Colloid Interface Sci., 449 (2015) 180–191.
6. C.B. Vidal, A.B. dos Santos, R.F. do Nascimento, T.J. Bandosz, Reactive adsorption of pharmaceuticals on tin oxide pillared montmorillonite: effect of visible light exposure, Chem. Eng. J., 259 (2015) 865–875.
7. F.A. Andersen, Final report on the safety assessment of isobutylparaben and isopropylparaben, J. Am. Coll. Toxicol., 14 (1995) 364–372.
8. M. Borremans, J. Van Loco, P. Roos, L. Goeyens, Validation of HPLC analysis of 2-phenoxyethanol, 1-phenoxypropan-2-ol, methyl, ethyl, propyl, butyl and benzyl 4-hydroxybenzoate (parabens) in cosmetic products, with emphasis on decision limit and detection capability, Chromatographia, 59 (2004) 47–53.
9. M.G. Soni, I.G. Carabin, G.A. Burdock, Safety assessment of esters of p-hydroxybenzoic acid (parabens), Food Chem. Toxicol., 43 (2005) 985–1015.
10. C. Radovan, D. Cinghiţaˇ, F. Manea, M. Mincea, C. Cofan, V. Ostafe, Electrochemical sensing and assessment of parabens in hydro-alcoholic solutions and water using a boron-doped diamond electrode, Sensors, 8 (2008) 4330–4349.
11. R.S. Tavares, F.C. Martins, P.J. Oliveira, J. Ramalho-Santos, F.P. Peixoto, Parabens in male infertility-Is there a mitochondrial connection?, Reprod. Toxicol., 27 (2009) 1–7.
12. W. Li, L. Gao, Y. Shi, Y. Wang, J. Liu, Y. Cai, Spatial distribution, temporal variation and risks of parabens and their chlorinated derivatives in urban surface water in Beijing, China, Sci. Total Environ., 539 (2016) 262–270.
13. J.A. Ocaña-González, M. Villar-Navarro, M. Ramos-Payán, R. Fernández-Torres, M.A. Bello-López, New developments in the extraction and determination of parabens in cosmetics and environmental samples. A review, Anal. Chim. Acta, 858 (2015) 1–15.
14. P.D. Darbre, A. Aljarrah, W.R. Miller, N.G. Coldham, M.J. Sauer, G.S. Pope, Concentrations of parabens in human breast tumours, J. Appl. Toxicol., 24 (2004) 5–13.
15. A.M. Aker, D.J. Watkins, L.E. Johns, K.K. Ferguson, O.P. Soldin, L.V. Anzalota Del Toro, A.N. Alshawabkeh, J.F. Cordero, J.D. Meeker, Phenols and parabens in relation to reproductive and thyroid hormones in pregnant women, Environ. Res., 151 (2016) 30–37.
16. H. Zhu, K. Kannan, Parabens in stretch mark creams: a source of exposure in pregnant and lactating women, Sci. Total Environ., 744 (2020) 141016, doi: 10.1016/j.scitotenv.2020. 141016.
17. J. Boberg, C. Taxvig, S. Christiansen, U. Hass, Possible endocrine disrupting effects of parabens and their metabolites, Reprod. Toxicol., 30 (2010) 301–312.
18. S. Shirai, Y. Suzuki, J. Yoshinaga, H. Shiraishi, Y. Mizumoto, Urinary excretion of parabens in pregnant Japanese women, Reprod. Toxicol., 35 (2013) 96–101.
19. J. Chen, K.C. Ahn, N.A. Gee, S.J. Gee, B.D. Hammock, B.L. Lasley, Antiandrogenic properties of parabens and other phenolic containing small molecules in personal care products, Toxicol. Appl. Pharmacol., 221 (2007) 278–284.
20. T. Wu, C. Wang, X. Wang, Q. Ma, Simultaneous determination of 21 preservatives in cosmetics by ultra performance liquid chromatography, Int. J. Cosmet. Sci., 30 (2008) 367–372.
21. M. Schlumpf, K. Kypke, M. Wittassek, J. Angerer, H. Mascher, D. Mascher, C. Vökt, M. Birchler, W. Lichtensteiger, Exposure patterns of UV filters, fragrances, parabens, phthalates, organochlor pesticides, PBDEs, and PCBs in human milk: correlation of UV filters with use of cosmetics, Chemosphere, 81 (2010) 1171–1183.
22. L. Wang, C. Liao, F. Liu, Q. Wu, Y. Guo, H.B. Moon, H. Nakata, K. Kannan, Occurrence and human exposure of p-hydroxybenzoic acid esters (parabens), bisphenol a diglycidyl ether (BADGE), and their hydrolysis products in indoor dust from the United States and three east Asian countries, Environ. Sci. Technol., 46 (2012) 11584–11593.
23. C. Li, X. Cui, Y. Chen, C. Liao, Paraben concentrations in human fingernail and its association with personal care product use, Ecotoxicol. Environ. Saf., 202 (2020) 110933, doi: 10.1016/j. ecoenv.2020.110933.
24. J. Gasperi, D. Geara, C. Lorgeoux, A. Bressy, S. Zedek, V. Rocher, A. El Samrani, G. Chebbo, R. Moilleron, First assessment of triclosan, triclocarban and paraben mass loads at a very large regional scale: case of Paris conurbation (France), Sci. Total Environ., 493 (2014) 854–861.
25. C.A. Galinaro, F.M. Pereira, E.M. Vieira, Determination of parabens in surface water from Mogi Guaçu River (São paulo, Brazil) using dispersive liquid–liquid microextraction based on low density solvent and LC-DAD, J. Braz. Chem. Soc., 26 (2015) 2205–2213.
26. C.B. Vidal, P.G.A. Barbosa, G.P. Pessoa, R.M. Cavalcante, R.F. Nascimento, Multiresidue determination of endocrine disrupting compounds in sewage treatment plants (SPEHPLC-DAD), J. Braz. Chem. Soc., 31 (2020) 1–13, doi: 10.21577/0103-5053.20200127.
27. C. Haman, X. Dauchy, C. Rosin, J.F. Munoz, Occurrence, fate and behavior of parabens in aquatic environments: a review, Water Res., 68 (2015) 1–11.
28. N. Paxéus, Organic pollutants in the effluents of large wastewater treatment plants in Sweden, Water Res., 30 (1996) 1115–1122.
29. N. Jonkers, A. Sousa, S. Galante-Oliveira, C.M. Barroso, H.P.E. Kohler, W. Giger, Occurrence and sources of selected phenolic endocrine disruptors in Ria de Aveiro, Portugal, Environ. Sci. Pollut. Res., 17 (2010) 834–843.
30. E. Carmona, V. Andreu, Y. Picó, Occurrence of acidic pharmaceuticals and personal care products in Turia River Basin: from waste to drinking water, Sci. Total Environ., 484 (2014) 53–63.
31. Y.L. Wei, L.J. Bao, C.C. Wu, E.Y. Zeng, Characterization of anthropogenic impacts in a large urban center by examining the spatial distribution of halogenated flame retardants, Environ. Pollut., 215 (2016) 187–194.
32. M.A.K. Silveira, S.S. Caldas, J.R. Guilherme, F.P. Costa, B.D.S. Guimarães, M.B.R. Cerqueira, B.M. Soares, E.G. Primel, Quantification of pharmaceuticals and personal care product residues in surface and drinking water samples by SPE and LC-ESI-MS/MS, J. Braz. Chem. Soc., 24 (2013) 1385–1395.
33. M.F. Luizete, Parabenos em água superficial: estudo analítico e aplicação em amostras ambientais, Master’s Thesis, Universidade Estadual Paulista, São Paulo, Brazil, 2013.
34. F.F. Sodré, P.M. Dutra, V.P. Dos Santos, Pharmaceuticals and personal care products as emerging micropollutants in Brazilian surface waters: a preliminary snapshot on environmental contamination and risks, Eclet. Quim., 43 (2018) 22–34.
35. M.M. dos Santos, F. de A. Brehm, T.C. Filippe, H.G. Knapik, J.C.R. de Azevedo, Occurrence and risk assessment of parabens and triclosan in surface waters of southern Brazil: a problem of emerging compounds in an emerging country, Rbrh, 21 (2016) 603–617.
36. C. Coelho, B. Heim, S. Foerster, A. Brosinsky, J.C. de Araújo, In situ and satellite observation of CDOM and chlorophyll-a dynamics in small water surface reservoirs in the Brazilian semiarid region, Water (Switzerland), 9 (2017), doi: 10.3390/ w9120913.
37. M.A.S. Cruz, A. de A. Gonçalves, R. de Aragão, J.R.A. de Amorim, P.V.M. da Mota, V.S. Srinivasan, C.A.B. Garcia, E.E. de Figueiredo, Spatial and seasonal variability of the water quality characteristics of a river in Northeast Brazil, Environ. Earth Sci., 78 (2019), doi: 10.1007/s12665-019-8087-5.
38. J. Xu, B. Chen, M. He, B. Hu, Analysis of preservatives with different polarities in beverage samples by dual-phase dual stir bar sorptive extraction combined with high-performance liquid chromatography, J. Chromatogr. A, 1278 (2013) 8–15.
39. L. Núñez, J.L. Tadeo, A.I. García-Valcárcel, E. Turiel, Determination of parabens in environmental solid samples by ultrasonic-assisted extraction and liquid chromatography with triple quadrupole mass spectrometry, J. Chromatogr. A, 1214 (2008) 178–182.
40. H. Shaaban, A. Mostafa, W. Alhajri, L. Almubarak, K. AlKhalifah, Development and validation of an eco-friendly SPE-HPLC-MS method for simultaneous determination of selected parabens and bisphenol A in personal care products: evaluation of the greenness profile of the developed method, J. Liq. Chromatogr. Related Technol., 41 (2018) 621–628.
41. C.B. Vidal, A.V. Feitosa, G.P. Pessoa, G.S.C. Raulino, A.G. Oliveira, A.B. dos Santos, R.F. Nascimento, Polymeric and silica sorbents on endocrine disruptors determination, Desal. Water Treat., 54 (2015) 156–165.
42. P.M.C. Buarque, R.B.P. de Lima, C.B. Vidal, H.L. de B. Buarque, P.I.M. Firmino, A.B. dos Santos, Enhanced removal of emerging micropollutants by applying microaeration to an anaerobic reactor, Eng. Sanit. Ambient., 24 (2019) 667–673.
43. A.V. Herrera-Herrera, M. Asensio-Ramos, J. Hernández- Borges, M.Á. Rodríguez-Delgado, Dispersive liquid–liquid microextraction for determination of organic analytes, TrAC, Trends Anal. Chem., 29 (2010) 728–751.
44. G. D’Orazio, M. Asensio-Ramos, J. Hernández-Borges, S. Fanali, M.Á. Rodríguez-Delgado, Estrogenic compounds determination in water samples by dispersive liquid–liquid microextraction and micellar electrokinetic chromatography coupled to mass spectrometry, J. Chromatogr. A, 57 (2014) 1–12.
45. M. Rezaee, Y. Assadi, M.R. Milani Hosseini, E. Aghaee, F. Ahmadi, S. Berijani, Determination of organic compounds in water using dispersive liquid–liquid microextraction, J. Chromatogr. A, 1116 (2006) 1–9.
46. M.L. Martins, E.G. Primel, S.S. Caldas, O.D. Prestes, M.B. Adaime, R. Zanella, Microextração Líquido-Líquido Dispersiva (DLLME): fundamentos e aplicações, Sci. Chromatogr., 4 (2012) 35–51.
47. Y. Wen, J. Li, W. Zhang, L. Chen, Dispersive liquid–liquid microextraction coupled with capillary electrophoresis for simultaneous determination of sulfonamides with the aid of experimental design, Electrophoresis, 32 (2011) 2131–2138.
48. Y. Han, X. Jia, X. Liu, T. Duan, H. Chen, DLLME Combined with GC–MS for the determination of methylparaben, ethylparaben, propylparaben and butylparaben in beverage samples, Chromatographia, 72 (2010) 351–355.
49. M.S. Noorashikin, S. Mohamad, M.R. Abas, Determination of parabens in water samples by cloud point extraction and aqueous two-phase extraction using high-performance liquid chromatography, Desal. Water Treat., 57 (2016) 22353–22361.
50. X. Shen, J. Liang, L. Zheng, Q. Lv, H. Wang, Application of dispersive liquid–liquid microextraction for the preconcentration of eight parabens in real samples and their determination by high-performance liquid chromatography, J. Sep. Sci., 40 (2017) 4385–4393.
51. C.A. Chávez-Moreno, L. Hinojosa-Reyes, E.J. Ruiz-Ruiz, A. Hernández-Ramírez, J.L. Guzmán-Mar, Optimization of solid-phase extraction of parabens and benzophenones in water samples using a combination of Plakett-Burman and Box-Behnken designs, J. Sep. Sci., 41 (2018) 4488–4497.
52. F.L.F. da Silva, J.P.S. Oliveira, V.M. Campos, S.T. Gouveia, L.P.D. Ribeiro, G.S. Lopes, W.O. Matos, Infrared radiation as a heat source in sample preparation of shrimp for trace element analysis, J. Food Compos. Anal., 79 (2019) 107–113.
53. F.F. De Oliveira, K.O. Moura, L.S. Costa, C.B. Vidal, A.R. Loiola, R.F. Do Nascimento, Reactive adsorption of parabens on synthesized micro- and mesoporous silica from coal fly ash: pH effect on the modification process, ACS Omega, 5 (2020) 3346–3357.
54. G. Derringer, R. Suich, Simultaneous optimization of several response variables, J. Qual. Technol., 12 (2018) 214–219.
55. N.R. Costa, J. Lourenço, Multiresponse problems: desirability and other optimization approaches, J. Chemom., 30 (2016) 702–714.
56. BRASIL, RDC N. 166, de 25 de Julho de 2017, Agência Nac. Vigilância Sanitária (ANVISA), 2017.
57. International Conference on Harmonization (ICH), ”Validation of Analytical Procedures: Text and Methodology” Q2 (R1), Geneva, 2005.
58. Instituto Brasileiro de Geografia e Estatística, No Title, Inst. Bras. Geogr. e Estatística, IBGE Cid. Fortaleza-CE. (2018) 1. Available at: https://cidades.ibge.gov.br/brasil/ce/fortaleza/ panorama (accessed May 7, 2021).
59. F. da Silva Peixoto, I.N. Cavalcante, D.F. Gomes, Influence of land use and sanitation issues on water quality of an urban aquifer, Water Resour. Manage., 34 (2020) 653–674.
60. A. Prichodko, V. Šakočiūtė, V. Vičkačkaitė, Dispersive liquid– liquid microextraction of parabens, Chemija, 21 (2010) 112–117.
61. M.I. Leong, M.R. Fuh, S. Da Huang, Beyond dispersive liquid–liquid microextraction, J. Chromatogr. A, 1335 (2014) 2–14.
62. C. Capello, U. Fischer, K. Hungerbühler, What is a green solvent? A comprehensive framework for the environmental assessment of solvents, Green Chem., 9 (2007) 927–934.
63. A. Gałuszka, Z.M. Migaszewski, P. Konieczka, J. Namieśnik, Analytical eco-scale for assessing the greenness of analytical procedures, TrAC, Trends Anal. Chem., 37 (2012) 61–72.
64. C. Moreta, M.-T. Tena, K. Kannan, Analytical method for the determination and a survey of parabens and their derivatives in pharmaceuticals, Environ. Res., 142 (2015) 452–460.
65. P. Hashemi, S. Beyranvand, R.S. Mansur, A.R. Ghiasvand, Development of a simple device for dispersive liquid–liquid microextraction with lighter than water organic solvents: isolation and enrichment of glycyrrhizic acid from licorice, Anal. Chim. Acta, 655 (2009) 60–65.
66. M.A. Farajzadeh, D. Djozan, R.F. Bakhtiyari, Use of a capillary tube for collecting an extraction solvent lighter than water after dispersive liquid–liquid microextraction and its application in the determination of parabens in different samples by gas chromatography-flame ionization detection, Talanta, 81 (2010) 1360–1367.
67. T. Angelov, A. Vlasenko, W. Tashkov, HPLC determination of pKa of parabens and investigation on their lipophilicity parameters, J. Liq. Chromatogr. Related Technol., 31 (2007) 188–197.
68. D. Błedzka, J. Gromadzińska, W. Wasowicz, Parabens. From environmental studies to human health, Environ. Int., 67 (2014) 27–42.
69. C.F. Grecco, I.D. Souza, V.R. Acquaro Junior, M.E.C. Queiroz, Determination of parabens in breast milk samples by dispersive liquid–liquid microextraction (DLLME) and ultra-high-performance liquid chromatography tandem mass spectrometry, J. Braz. Chem. Soc., 30 (2019) 48–59.
70. R. Jain, M.K.R. Mudiam, A. Chauhan, Ratnasekhar Ch, R.C. Murthy, H.A. Khan, Simultaneous derivatisation and preconcentration of parabens in food and other matrices by isobutyl chloroformate and dispersive liquid–liquid microextraction followed by gas chromatographic analysis, Food Chem., 141 (2013) 436–443.
71. N. Raza, K.H. Kim, M. Abdullah, W. Raza, R.J.C. Brown, Recent developments in analytical quantitation approaches for parabens in human-associated samples, TrAC, Trends Anal. Chem., 98 (2018) 161–173.
72. European Commission Directorate General For Health And Food Safety, Analytical Quality Control and Method Validation for Pesticide Residues Analysis in Food and Feed (SANTE/12682/2019), Sante/12682/2019, 2019, pp. 1–48.
73. S. Gülle, H.I. Ulusoy, A. Kabir, A. Tartaglia, K.G. Furton, M. Locatelli, V.F. Samanidou, Application of a fabric phase sorptive extraction-high performance liquid chromatographyphotodiode array detection method for the trace determination of methyl paraben, propyl paraben and butyl paraben in cosmetic and environmental samples, Anal. Methods, 11 (2019) 6136–6145.
74. M. Becerra-Herrera, V. Miranda, D. Arismendi, P. Richter, Chemometric optimization of the extraction and derivatization of parabens for their determination in water samples by rotating-disk sorptive extraction and gas chromatography mass spectrometry, Talanta, 176 (2018) 551–557.
75. A.V. Marta-Sanchez, S.S. Caldas, A. Schneider, S.M.V.S. Cardoso, E.G. Primel, Trace analysis of parabens preservatives in drinking water treatment sludge, treated, and mineral water samples, Environ. Sci. Pollut. Res., 25 (2018) 14460–14470.
76. G. Reichert, S. Hilgert, S. Fuchs, J.C.R. Azevedo, Emerging contaminants and antibiotic resistance in the different environmental matrices of Latin America, Environ. Pollut., 255 (2019), doi: 10.1016/j.envpol.2019.113140.
77. S. de A.M. de Araújo, Validação de um método analítico (SPEHPLC) para determinação de compostos emergentes em águas superficiais, Doctoral Thesis,Universidade Federal do Ceará, Ceará, Brazil, 2014.
78. R.E. Carlson, A trophic state index for lakes, Limnol. Oceanogr., 22 (1977) 361–369.
79. W.D. Paulino, R. Reis, A. Oliveira, F.F. Avelino, Classificação Do Estado Trófico Para O Gerenciamento De Reservatórios No Semiárido: a Experiência Da Cogerh No Estado Ceará Classification for Trophic State in the Semiarid Reservoir Management: the Experience of Ceará, Abrh., 2013, pp. 1–8.
80. P.C.V. de Morais, A.F. Gama, G.M. Fernandes, A.H.B. Oliveira, M.F.B. Lima, F.R. dos Santos, D.A. Martins, R.F. Nascimento, R.M. Cavalcante, Emerging and traditional organic markers in areas with multiple anthropogenic activities: development of an analytical protocol and its application in environmental assessment studies, Bull. Environ. Contam. Toxicol., 102 (2019) 66–76.